The Kerr
effect, also called the quadratic
electro-optic effect (QEO effect), is a change in the refractive index
of a material in response to an applied electric field.
The Kerr effect is distinct from the Pockels effect
in that the induced index change is directly proportional to the square of
the electric field instead of varying linearly with it. All materials show a
Kerr effect, but certain liquids display it more strongly than others. The Kerr
effect was discovered in 1875 by John Kerr, a Scottish physicist.
Two special cases of the Kerr effect are normally
considered, these being the Kerr electro-optic effect, or DC Kerr effect, and
the optical Kerr effect, or AC Kerr effect.
Kerr electro-optic effect
The Kerr electro-optic effect, or DC Kerr effect,
is the special case in which a slowly varying external electric field is
applied by, for instance, a voltage on electrodes across the sample material. Under this
influence, the sample becomes birefringent,
with different indices of refraction for light polarized parallel to or perpendicular to
the applied field. The difference in index of refraction, Δn, is given
by

where λ is the wavelength of the light, K
is the Kerr constant, and E is the strength of the electric
field. This difference in index of refraction causes the material to act like a
waveplate
when light is incident on it in a direction perpendicular to the electric
field. If the material is placed between two "crossed"
(perpendicular) linear polarizers, no light will be transmitted when the electric
field is turned off, while nearly all of the light will be transmitted for some
optimum value of the electric field. Higher values of the Kerr constant allow
complete transmission to be achieved with a smaller applied electric field.
Some polar
liquids, such as nitrotoluene (C7H7NO2)
and nitrobenzene
(C6H5NO2) exhibit very large Kerr constants. A
glass cell filled with one of these liquids is called a Kerr cell. These
are frequently used to modulate light, since the Kerr effect responds very quickly to
changes in electric field. Light can be modulated with these devices at
frequencies as high as 10 GHz. Because the Kerr effect is relatively weak, a typical
Kerr cell may require voltages as high as 30 kV
to achieve complete transparency. This is in contrast to Pockels cells,
which can operate at much lower voltages. Another disadvantage of Kerr cells is
that the best available material, nitrobenzene,
is poisonous. Some transparent crystals have also been used for Kerr
modulation, although they have smaller Kerr constants.
In media that lack inversion symmetry, the Kerr effect is
generally masked by the much stronger Pockels
effect. The Kerr effect is still present, however, and in many cases
can be detected independently of Pockels effect contributions.
Optical Kerr effect
The optical Kerr effect, or AC Kerr effect is the
case in which the electric field is due to the light itself. This causes a
variation in index of refraction which is proportional to the local irradiance
of the light. This refractive index variation is responsible for the nonlinear
optical effects of self-focusing,
self-phase modulation and modulational instability, and is the basis
for Kerr-lens modelocking. This effect only
becomes significant with very intense beams such as those from lasers.
Magneto-optic Kerr effect
Main article: Magneto-optic Kerr effect
The magneto-optic Kerr effect (MOKE) is the
phenomenon that the light reflected from a magnetized material has a slightly
rotated plane of polarization. It is similar to the Faraday effect
where the plane of polarization of the transmitted light is rotated.
Theory
DC Kerr effect
where ε0 is the vacuum permittivity
and χ(n) is the n-th order component of the electric susceptibility of the medium. The
":" symbol represents the scalar product between matrices. We can
write that relationship explicitly; the i-th component for the vector P
can be expressed as:
where
. It is often
assumed that
, i.e. the
component parallel to x of the polarization field;
and so on.
For a linear medium, only the first term of this
equation is significant and the polarization varies linearly with the electric
field.
For materials exhibiting a non-negligible Kerr
effect, the third, χ(3) term is significant, with the even-order
terms typically dropping out due to inversion symmetry of the Kerr medium.
Consider the net electric field E
produced by a light wave of frequency ω together with an external electric
field E0:
where Eω
is the vector amplitude of the wave.
Combining these two equations produces a complex
expression for P. For the DC
Kerr effect, we can neglect all except the linear terms and those in
:
which is similar to the linear relationship
between polarization and an electric field of a wave, with an additional
non-linear susceptibility term proportional to the square of the amplitude of
the external field.
For non-symmetric media (e.g. liquids), this
induced change of susceptibility produces a change in refractive index in the
direction of the electric field:
where λ0 is the vacuum wavelength
and K is the Kerr constant for the medium. The applied field
induces birefringence in the medium in the direction of
the field. A Kerr cell with a transverse field can thus act as a switchable wave plate,
rotating the plane of polarization of a wave travelling through it. In
combination with polarizers, it can be used as a shutter or modulator.

For crystals, the susceptibility of the medium will in general be
a tensor,
and the Kerr effect produces a modification of this tensor.
AC Kerr effect
In the optical or AC Kerr effect, an intense beam
of light in a medium can itself provide the modulating electric field, without
the need for an external field to be applied. In this case, the electric field
is given by:
where Eω
is the amplitude of the wave as before.
Combining this with the equation for the
polarization, and taking only linear terms and those in χ(3)|Eω|3::81–82
As before, this looks like a linear
susceptibility with an additional non-linear term:
and since:
where n0=(1+χLIN)1/2
is the linear refractive index. Using a Taylor
expansion since χNL << n02,
this gives an intensity dependent refractive index (IDRI) of:
where n2 is the second-order
nonlinear refractive index, and I is the intensity of the wave. The
refractive index change is thus proportional to the intensity of the light
travelling through the medium.
The values of n2 are relatively
small for most materials, on the order of 10−20 m2 W−1
for typical glasses. Therefore beam intensities (irradiances)
on the order of 1 GW cm−2 (such as those produced by lasers) are
necessary to produce significant variations in refractive index via the AC Kerr
effect.
The optical Kerr effect manifests itself
temporally as self-phase modulation, a self-induced phase- and frequency-shift
of a pulse of light as it travels through a medium. This process, along with dispersion, can produce optical solitons.
Spatially, an intense beam of light in a medium
will produce a change in the medium's refractive index that mimics the
transverse intensity pattern of the beam. For example, a Gaussian beam
results in a Gaussian refractive index profile, similar to that of a gradient-index lens. This causes the beam to
focus itself, a phenomenon known as self-focusing.
As the beam self-focuses, the peak intensity increases
which, in turn, causes more self-focusing to occur. The beam is prevented from
self-focusing indefinitely by nonlinear effects such as multiphoton ionization, which become
important when the intensity becomes very high. As the intensity of the
self-focused spot increases beyond a certain value, the medium is ionized by
the high local optical field. This lowers the refractive index, defocusing the
propagating light beam. Propagation then proceeds in a series of repeated
focusing and defocusing steps. SOURCE :
http://en.wikipedia.org/wiki/Kerr_effect